Thursday, September 14, 2006

New type of hydrogen fuel cell powers up -

"Within a few years, laptops and other energy-guzzling portable devices could run on long-lasting, easily recharged fuel cells based on a safe and practical new way of storing and releasing hydrogen.
Chemist Don Gervasio and colleague Sonja Tasic, both at Arizona State University in the US, set out to develop a fuel cell that would generate more electricity for its weight than the best batteries, and would also work at room temperature.
Gervasio's solution was to use the alkaline compound borohydride. A 30% solution of borohydride in water actually contains one-third more hydrogen than the same volume of liquid hydrogen.
'The difference is that the borohydride is at room temperature, and it's stable, non-toxic and cost-effective,' Gervasio says.
Quick recharge
The borohydride solution releases its hydrogen as it flows over a catalyst made of ruthenium. The hydrogen passes through a membrane and combines with oxygen in the fuel cell, generating electricity and waste water.
Theoretically, this could achieve an energy density up to about 2200 watt-hours per litre Gervasio says, compared to 200 watt-hours per litre for a lithium polymer battery.
'For the same size and weight you can make a lot more electricity, so your laptop or camcorder will run a lot longer,' he says.
Clogged up
However, Gervasio's early systems ran into trouble when the hydrogen-generating cells became clogged with insoluble boron oxide. His team looked for something that would dissolve boron oxide, and found it in a widely-used material: ethylene glycol, otherwise known as antifreeze. The ethylene glycol also had no effect on hydrogen generation.
The researchers can now run the hydrogen generator on a 15% sol"

No comments: